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Hello I am trying to prepare D-Tyrosine from crresponding hydantion by using enzyme called hydantoinase.After getting the N-carbamoyl D-aminoacid, i have to do diazotisation by using NaNO2/HCl.there are many reports in literature using this method.But when i tried for N-carbamoyl D-tyrosine in acidic medium at temp0-5C using NaNO2, the yield is very low(20%). Can any body suggests is there any other route to improve the yield up to 60-70% thank you Koteshwar -- Paul J. Franklin(moderator - sci.chem.organic.synthesis) http://organicworldwide.net/sci.chem.organic.synthesis Georgia State University <[EMAIL PROTECTED]> Atlanta, GA
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